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Deionized Water

 DEIONIZED WATER

Years ago, high purity water was used only in limited applications. Today, deionized (Dl) water has become an essential ingredient in hundreds of applications including: medical, laboratory, pharmaceutical, cosmetics, electronics manufacturing, food processing, plating, countless industrial processes, and even the final rinse at the local car wash.

THE DEIONIZATION PROCESS
The vast majority of dissolved impurities in modern water supplies are ions such as calcium, sodium, chlorides, etc. The deionization process removes ions from water via ion exchange. Positively charged ions (cations) and negatively charged ions (anions) are exchanged for hydrogen (H+) and hydroxyl (OH-) ions, respectively, due to the resin's greater affinity for other ions. The ion exchanges process occurs on the binding sites of the resin beads. Once depleted of exchange capacity, the resin bed is regenerated with concentrated acid and caustic which strips away accumulated ions
through physical displacement, leaving hydrogen or hydroxyl ions in their
place.

DEIONIZER TYPES
Deionizers exist in four basic forms: disposable cartridges, portable exchange tanks, automatic units, and continuous units. A two-bed system employs separate cation and anion resin beds.
Mixed-bed deionizers utilize both resins in the same vessel. The highest quality water is produced by mixed-bed deionizers, while two-bed deionizers have a larger capacity.
Continuous deionizers, mainly used in labs for polishing, do not require regeneration.

TESTING Dl WATER QUALITY
Water quality from deionizers varies with the type of resins used, feed water quality, flow, efficiency of regeneration, remaining capacity, etc. Because of these variables, it is critical in many Dl water applications to know the precise quality. Resistivity/conductivity is the most convenient method for testing Dl water quality. Deionized pure water is a poor electrical conductor, having a resistivity of 18.2 million ohm-cm (18.2 megohm) and conductivity of 0.055 microsiemens. It is the amount of ionized substances (or salts) dissolved in the water which determines water's ability to conduct electricity. Therefore, resistivity and its inverse, conductivity, are good general purpose quality parameters.

Because temperature dramatically affects the conductivity of water, conductivity measurements are internationally referenced to 25șC to allow for comparisons of different samples. With typical water supplies, temperature changes the conductivity an average of 2%/ șC, which is relatively easy to compensate. Deionized water, however, is much more challenging to accurately measure since temperature effects can approach 10%/șC! Accurate automatic temperature compensation, therefore, is the "heart" of any respectable instrument.


RECOMMENDED INSTRUMENTATION:

Hand-held instruments are typically used to measure Dl water quality at points of use, pinpoint problems in a Dl system, confirm monitor readings, and test the feed water to the system. The hand-held Myron L instruments have been the first choice of Dl water professionals for many years. For two-bed Dl systems, there are several usable models with displays in either microsiemens or ppm (parts per million) of total dissolved solids. The most versatile instrument for Dl water is the 4P or 6P ULTRAMETER™, which can measure both ultra pure mixed-bed quality water and unpurified water. It should be noted that once Dl water leaves the piping, its resistivity will drop because the water absorbs dissolved carbon dioxide from the air.

In-line monitor/controllers are generally used in the more demanding Dl water applications.
Increased accuracy is realized since the degrading effect of carbon dioxide on high purity water is avoided by use of an in-line sensor (cell). This same degradation of ultra pure water is the reason there are no resistivity calibration standard solutions (as with conductivity instruments).
Electronic sensor substitutes are used to calibrate resistivity monitor/controllers.

Myron L manufactures a variety of in-line instruments, including resistivity monitor/controllers which are designed specifically for Dl water. Seven resistivity ranges are available from 0-200 KW to 0-20 MW to suit any Dl water application. Temperature compensation is automatic and achieved via a dual thermistor circuit. All models contain an internal adjustable set point, piezo alarm connectors and a heavy-duty 10 amp relay circuit which can be used to control an alarm,
valves, pump, etc. Available options include 4-20 milliamp output, 3 cell input and 3 range capability.

Sensors are available constructed in either 316 stainless steel or titanium. All cells are provided with a 3/4" MNPT polypropylene bushing and 10' (3 meters) cable. Optional PVDF or stainless steel bushings can be ordered, as well as longer cable lengths up to 100 feet (30 meters).

 


Useful Conversions:
1/megohm = microsiemens (micromhos)
1/microsiemens (micromhos) = Megohm

Examples:
0.5 microsiemens = 2 megohm (2,000,000 ohms)
200 kilohm (200,000 ohms) = 0.2 megohm = 5 microsiemens

Click here for Ultra meter specifications and prices

December, 2005
Reprint of Myron L Co application bulletin.

Prices: If there is a difference in the prices shown, customers will be contacted for approval before processing the order.
 

Prices do not include shipping charges.


Terms: Net 30 days 


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GWJ co
Hacienda Heights, California
 
Phone: 626-336-1134  800-336-1138 (USA)
Fax: 626-336-2409

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